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In one picture, the Oscar winner is seen sporting a flowing evening dress and hat, topped off with a pair of long white socks and chunky Dr Martens boots.
Others see the pouting teenager clad in a swimwear, leopard printed dress and denim shorts and a crop top.
Before making it big in Hollywood, Jolie, the daughter of actor Jon Voight, became a model in her teens. She as a student studied drama.
The pictures will be up for grab at an auction. As part of an original glamour photography event, there will alos be pictures of young George Clooney, Drew Barrymore, Kirsten Dunst, Teri Hatcher, Sarah Jessica Parker, Ann-Margret, Halle Berry, Cher, Diana Ross, Will Smith and Rock Hudson.
There is also a collection of master prints by artists such as Richard Avedon, Man Ray, Helmut Newton and Herb Ritts.